DBP N-nitrosodimethyamine, haloacetonitriles, haloacetaldehydes

Environ Sci Technol. 2009 Nov 1;43 (21):8320-8325 19924963 (P,S,G,E,B,D)
Water Quality Laboratory, Metropolitan Water District of Southern California, 700 Moreno Avenue, La Verne, California 91750, Department of Civil, Environmental and Sustainable Engineering, Engineering Center (G-Wing), Arizona State University, Room ECG-252, Tempe, Arizona 85287-5306, Center for Environmental Biotechnology, Biodesign Institute, Arizona State University, P.O. Box 875701, Tempe, Arizona 85287-5701, and King Abdullah University of Science and Technology, Box 55455, Jeddah, 21534, Saudi Arabia.
Effluents from wastewater treatment plants (WWTPs) contain disinfection byproducts (DBPs) of health concern when the water is utilized downstream as a potable water supply. The pattern of DBP formation was strongly affected by whether or not the WWTP achieved good nitrification. Chlorine addition to poorly nitrified effluents formed low levels of halogenated DBPs, except for (in some cases) dihalogenated acetic acids, but often substantial amounts of N-nitrosodimethyamine (NDMA). Chlorination of well-nitrified effluent typically resulted in substantial formation of halogenated DBPs but much less NDMA. For example, on a median basis after chlorine addition, the well-nitrified effluents had 57 mug/L of trihalomethanes [THMs] and 3 ng/L of NDMA, while the poorly nitrified effluents had 2 mug/L of THMs and 11 ng/L of NDMA. DBPs with amino acid precursors (haloacetonitriles, haloacetaldehydes) formed at substantial levels after chlorination of well-nitrified effluent. The formation of halogenated DBPs but not that of NDMA correlated with the formation of THMs in WWTP effluents disinfected with free chlorine. However, THM formation did not correlate with the formation of other DBPs in effluents disinfected with chloramines. Because of the relatively high levels of bromide in treated wastewater, bromine incorporation was observed in various classes of DBPs.
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